Raman and luminescence studies of potassium bromide and potassium iodide crystals. by Gervase Vincent McKinley

Cover of: Raman and luminescence studies of potassium bromide and potassium iodide crystals. | Gervase Vincent McKinley

Published .

Written in English

Read online

Edition Notes

Thesis (Ph. D.)--The Queen"s University of Belfast, 1975.

Book details

The Physical Object
Pagination1 v
ID Numbers
Open LibraryOL21221150M

Download Raman and luminescence studies of potassium bromide and potassium iodide crystals.

POTASSIUM bromide has a crystal structure similar to that of rocksalt ; but as the ions in the former are heavier, the Raman frequency shifts are smaller and hence less easy to record in a Cited by: 5. Studies on Raman Effect in Single Crystals of Potassium Nitrate In the case of KNO 3 the tilting oscillation has a much lower frequency, nearly half that of NaNO 3, whereas the symmetrical oscillation of the NO3 ion has practically the same value.

Hence, it is but natural to expect that the line 82 should be stronger than the line This monograph for Potassium Bromide provides, in addition to common physical constants, a general description including typical appearance, applications, change. IDENTIFICATION: Potassium bromide is a white crystalline powder or granule.

It is odorless and has a strong, bitter taste. It is soluble in water. USE: Potassium bromide is an important commercial chemical. It is used in human and animal veterinary medicine as a sedative and anti-seizure medication.

Potassium Bromide ( -3) LC50 fish 1 > 30 mg/l Persistence and degradability Potassium Bromide ( -3) Persistence and degradability May cause long-term adverse effects in the environment.

Bioaccumulative potential Potassium Bromide ( -3) Bioaccumulative potential Not established. Mobility in soilFile Size: KB. Potassium Bromide. Potassium bromide is a halide salt most commonly used as an add-on anticonvulsant drug to phenobarbital when the latter is ineffective or not as effective as desired.

It also may permit you to decrease the dose level of the phenobarbital. Potassium bromide may also be used initially as the sole anticonvulsant drug.

Sigma-Aldrich offers a number of Potassium bromide products. View information & documentation regarding Potassium bromide, including CAS, MSDS & more. However, on a Raman machine with an ordinary cutoff Rayleigh filter you will see only Stokes part of the luminescence.

And, probably, the choice of a laser for excitation in this case won't matter. One way to make potassium bromide is to react the hydroxide with hydrobromic acid. The resulting salt can then be purified by recrystallization. KOH(aq) + HBr(aq) → KBr(aq) + H 2 O(l) While not a normal route of preparation because of the expense, potassium metal reacts vigorously with all the halogens to form potassium halides.

In fact, many studies on the Raman spectra of MAPbI 3 show features also attributable to the Raman spectrum of PbI 2 38, suggesting that severe sample degradation might have Cited by: Raman and infrared spectral studies of anhydrous potassium and rubidium carbonate the magnitude of LO-TO splitting and the infraxed intensities are also proportional to the values of (du%oQ)2, then it is expected that the relative magnitudes of u-u and g-a c.f.

splitting as well as the relative magnitudes of LO-TO splitting for the Cited by: Preparation. Potassium bromate is produced when bromine is passed through a hot solution of potassium first forms unstable potassium hypobromite, which quickly disproportionates into bromide and bromate.

3BrO − (aq) → 2Br − (aq) + BrO − 3 (aq). Electrolysis of potassium bromide solutions will also give bromate. Both processes are analogous to those used in the Chemical formula: KBrO₃. Synthesis of potassium bromate from potassium bromide Sign in to follow this.

I`ve done it with Sodium Iodide/ate and it worked quite well, although with carbon electrodes the crystals never turn out the color they`re suposed to be, they turn a sort of Chocolate color, it`s the nature of the crystal formation, it traps in a lot of.

Raman spectrum of a single crystal of potassium sulphamate has been recorded for the first time usingλ radiation of mercury as the exciter. Thirty-three Raman lines have been observed of which nine belong to the lattice oscillations.

The infra-red absorption spectrum of the substance was taken in the powder form in potassium bromide disc using Carl Zeiss UR 10 IR by: 3. Vibrational spectral studies of solutions at elevated temperatures and pressures.

Raman spectral study of aqueous cadmium bromide solutions at 25 and C. Journal of Solution Chemistry17 (8), DOI: /BF Khin Nwe Soe, Hidekazu Doe, Toyokichi by: Other articles where Potassium bromide is discussed: spectroscopy: Infrared instrumentation: (ZnSe), cesium iodide (CsI), or potassium bromide (KBr), coated with silicon or germanium are employed.

Below cm−1 Mylar films of varying thickness are used to cover narrow portions of the region. Thermal detection of infrared radiation is based on the conversion of a temperature change.

Properties Chemical. Potassium bromide's properties are very similar to potassium reaction with sulfuric acid produces hydrobromic acid, in the same way the chloride analogue produces hydrochloric acid.

However, bromine is not as strong an oxidizer as chlorine, so chlorine will form bromine if reacted with a solution of bromide. 2 KBr + Cl 2 → 2 KCl + Br 2Appearance: White solid. Raman spectroscopy is an inelastic light scattering technique that was previously used with success in studies on several molten salt systems [] including MgCl 2 [7].

In the case of molten MgCl 2, a clearly resolved band was observed at cm-1 that was assigned to the symmetric stretch of the tetrahedral MgCl 4 2-species.

Other studiesFile Size: KB. \\- brō- mīd\\ n () A crystalline salt KBr with a saline taste that is used as a sedative and in photography. Abstract. Potassium bromate (KBrO3) is an oxidizing agent that has been used as a food additive, mainly in the bread-making process.

Although adverse effects are not evident in animals fed bread-based diets made from flour treated with KBrO3, the agent is carcinogenic in rats and nephrotoxic in both man and experimental animals when given by: Potassium Bromide, Crystal, Reagent, ACS, is found as a white crystal and is very soluble in water.

In infrared spectroscopy, samples are analyzed by grinding with powdered potassium bromide and pressing into a disc. As an ACS grade Reag. Raman spectra have been measured in both pure and alkali doped potassium lithium niobate (KLN) crystals.

One of the A(1)(TO) Raman modes at about approximate to cm(-1) measured in x(zz)x. High quality AlN single crystals grown by physical vapour transport and by sublimation of AlN powder were investigated by Raman, photoluminescence (PL) and absorption spectroscopy.

Absorption edges of the AlN single crystals varying from eV to eV as determined by transmission measurements. Near. Note: Citations are based on reference standards.

However, formatting rules can vary widely between applications and fields of interest or study. The specific requirements or preferences of your reviewing publisher, classroom teacher, institution or organization should be applied. Studies on the Raman effect in crystalline ammonium bromide ate very seanty.

tate the growth of crystals in the form of cubes a smaU quantity of urea was added to the solution. Photographs of the Raman spectrum of ammonium bromide taken at * T., ~ T. Potassium bromide Oral 50 mg/kg Non-applicable mg/kg Non-applicable CAS: Dermal 95 mg/kg Non-applicable 95 mg/kg Non-applicable EC: Inhalation Non-applicable Non-applicable mg/m³ Non-applicable PNEC: Identification Potassium bromide STP mg/L Fresh water mg/L CAS: Soil mg/kg Marine water 41 mg/L.

Potassium Bromide is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Most metal bromide compounds are water soluble for uses in water treatment, chemical analysis and in ultra high purity for certain crystal growth applications. Structure, properties, spectra, suppliers and links for: Potassium bromide, The above is the search results for Chinese Potassium Bromide, click for more recommended manufacturers & suppliers listings such as kbr,kbr price.

The global chemicals industry faces economic and environmental pressures, that's why many of our suppliers like Potassium Bromide factory are always innovating to provide more effective.

The Raman intensity spectra of potassium phosphate and diphosphate in aqueous solution have been measured against perchlorate solution as an external standard.

Including the intensities of triphosphate, proportionality was found between the total trace scattering, which covers the P O stretch frequencies only, and the number of P O by: 7. Potassium ions play pivotal roles in biological systems.

A simple and effective Raman scattering-based protocol for the detection of physiological potassium ions level in human serum has been developed. We employed sodium cobaltinitrite, which can react with potassium to form potassium-sodium by: 3. Europe PMC is an Elixir Core Data Resource Learn more ›.

Europe PMC is a service of the Europe PMC Funders' Group, in partnership with the European Bioinformatics Institute; and in cooperation with the National Center for Biotechnology Information at the U.S. National Library of Medicine (NCBI/NLM).It includes content provided to the PMC International archive by participating Cited by: 5.

potassium bromide skc-file Physical appearance: colorless cubic crystals Empirical formula (Hill's system for organic substances): BrK Structural formula as text: KBr Molar/atomic mass: Melting point (°C): Boiling point (°C): Solubility (g/ g of solvent): 1.

Symbol which looks like a small house Solid circle with an upward pointer in it. Jump to content. This paper describes a Raman study of enzyme reactions that use potassium ferricyanide as a reaction mediator.

The enzyme reaction systems investigated consisted of glucose oxidase (GOD), glucose, and potassium ferricyanide, and of lactate oxidase (LOD), lactate, and potassium by: 5. High quality AlN single crystals grown by physical vapour transport and by sublimation of AlN powder were investigated by Raman, photoluminescence (PL) and absorption spectroscopy.

Absorption edges of the AlN single crystals varying from eV to eV as determined by transmission by: RAMAN MICROSCOPE STUDY ON POTASSIUM CHROMATE CRYSTALS FORMED ON STAINLESS STEEL SURFACE Figure 2.

RAMAN maps on potassium chromate (yellow) and oxide (blue). The different forms of corrosion products on steel surfaces were identified using Bio-Rad RAMAN libraries (Figure 3 and 4). Figure 3. Spectra of the crystal and database search result.

Potassium Bromide is used in photographic processing, as a chemical intermediate for the manufacture of various chemicals, and bromides. It is used for water clarification.

Pharmaceutical grade is used in medicine as sedatives. The Raman spectrum of single crystals of KN 3 has been investigated over the frequency range from 30 to cm − ``unit cell'' method of Bhagavantam and Venkatarayudu was used to classify the normal modes and to derive their selection rules.

In addition to making available the Raman shifts for KN 3 crystals, this work also provides a check on assignments of much of the fine structure Cited by: Potassium bromide (KBr) is a salt, widely used as an anticonvulsant and a in the late 19th and early 20th centuries, with over-the-counter use extending to in the US.

Its action is due to the bromide ion (sodium bromide is equally effective). Potassium bromide is used as a veterinary drug, as an antiepileptic medication for dogs.

Objective—To critically evaluate and summarize available information on the safety of potassium bromide in dogs. Design—Systematic review.

Sample— references reporting safety information relevant to potassium bromide published between and Procedures—PubMed searches without date limitations were conducted with the terms “potassium bromide” and “sodium bromide Cited by: Minescus cement have bright luminescence which indicates meteoric vadose cement.

Poikilotopic sparry calcite cement is recognized by its very large crystals with the ability to enclose several grains. Under catho- Micro-Raman Spectroscopy and Luminescence Studies () pdf. We present an experimental set-up permitting Raman and luminescence spectroscopy studies in a commercial Physical Properties Measurement System (PPMS) from Quantum Design.

Using this experimental set-up, gaseous, liquid and solid materials, in bulk or thin film form, may be investigated. The set-up is particularly suitable for the study of the spin-lattice coupling in strongly Author: Matthias Hudl, Matthias Hudl, Peter Lazor, Roland Mathieu, Alexander G Gavriliuk, Viktor V Struzhkin.

30418 views Saturday, November 28, 2020